Chiral trialkoxysilanols derived from terpene alcohols. Molecular structures of tris([(1S)-endo]-(-)-bornoxy)silanol and tetrakis((-)-menthoxy)silane
| Data(s) |
01/04/2002
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|---|---|
| Resumo |
Terpene alcohols (−)-menthol and [(1<i>S</i>)-endo]-(−)-borneol react with SiCl<sub>4</sub> in the presence of base to give (MenO)<sub>3</sub>SiCl (<b>1</b>) and (BorO)<sub>3</sub>SiCl (<b>2</b>) in high yields. Hydrolysis of <b>1</b> yields (MenO)<sub>3</sub>SiOH (<b>4</b>) and (MenO)<sub>4</sub>Si (<b>3</b>). Hydrolysis of <b>2</b> yields only (BorO)<sub>3</sub>SiOH (<b>5</b>). The crystal structures of <b>3</b> and <b>5</b> are reported.<br /><br /><br /> |
| Identificador | |
| Idioma(s) |
eng |
| Publicador |
Elsevier Science SA |
| Relação |
http://dro.deakin.edu.au/eserv/DU:30001560/n20020434.pdf http://dx.doi.org/10.1016/S0022-328X(01)01420-6 |
| Direitos |
2002, Elsevier Science B.V. |
| Palavras-Chave | #trialkoxysilanols #chiral #terpenes |
| Tipo |
Journal Article |
