An epoxide ring-opening approach for a short and stereoselective synthesis of icetexane diterpenoids
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
|---|---|
| Data(s) |
20/10/2012
20/10/2012
2010
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| Resumo |
A new approach for the synthesis of the core skeleton of icetexane diterpenoids is presented and deals with an epoxide ring-opening reaction by metallated aromatic compounds. Employing this strategy, a short synthesis of an icetexane analogue of brussonol was achieved in just four steps from 2-allyl-cyclohexanone. (C) 2009 Elsevier Ltd. All rights reserved. FAPESP Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) CNPq Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) |
| Identificador |
TETRAHEDRON LETTERS, v.51, n.4, p.686-688, 2010 0040-4039 http://producao.usp.br/handle/BDPI/31687 10.1016/j.tetlet.2009.11.108 |
| Idioma(s) |
eng |
| Publicador |
PERGAMON-ELSEVIER SCIENCE LTD |
| Relação |
Tetrahedron Letters |
| Direitos |
closedAccess Copyright PERGAMON-ELSEVIER SCIENCE LTD |
| Palavras-Chave | #(+/-)-ABROTANONE #(+/-)-BRUSSONOL #KOMAROVIQUINONE #Chemistry, Organic |
| Tipo |
article original article publishedVersion |
