Preparation of alpha,beta-Unsaturated Diazoketones Employing a Horner-Wadsworth-Emmons Reagent
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
|---|---|
| Data(s) |
20/10/2012
20/10/2012
2011
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| Resumo |
A new method for the preparation of alpha,beta-unsaturated diazoketones from aldehydes and a Horner-Wadsworth- Emmons reagent is reported. The method was applied to the short synthesis of two substituted pyrrolidines. FAPESP (Research Supporting Foundation of the State of Sao Paulo) Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) CNPq Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) |
| Identificador |
JOURNAL OF ORGANIC CHEMISTRY, v.76, n.1, p.289-292, 2011 0022-3263 http://producao.usp.br/handle/BDPI/31649 10.1021/jo1021844 |
| Idioma(s) |
eng |
| Publicador |
AMER CHEMICAL SOC |
| Relação |
Journal of Organic Chemistry |
| Direitos |
restrictedAccess Copyright AMER CHEMICAL SOC |
| Palavras-Chave | #ALPHA-DIAZOCARBONYL COMPOUNDS #ARNDT-EISTERT SYNTHESIS #ENANTIOSELECTIVE SYNTHESES #DIAZO KETONES #ACID #DIAZOMETHANE #INHIBITORS #ALKALOIDS #ALDEHYDES #CHLORIDE #Chemistry, Organic |
| Tipo |
article original article publishedVersion |
