Ring Contraction of 1,2-Dihydronaphthalenes Promoted by Thallium(III) in Acetonitrile: A Diastereoselective Approach to Indanes
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
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| Data(s) |
20/10/2012
20/10/2012
2009
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| Resumo |
trans-1,3-Disubstituted indanes are conveniently accessed by a stereoselective ring contraction of 1,2-dihydronaphthalenes upon treatment with thallium(III) nitrate (TTN) in acetonitrile. Under these conditions, the oxidative rearrangement of either di- or trisubstituted double bonds is possible. FAPESP Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) CNPq Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) |
| Identificador |
SYNTHESIS-STUTTGART, n.3, p.385-388, 2009 0039-7881 http://producao.usp.br/handle/BDPI/31527 10.1055/s-0028-1083308 |
| Idioma(s) |
eng |
| Publicador |
GEORG THIEME VERLAG KG |
| Relação |
Synthesis-stuttgart |
| Direitos |
closedAccess Copyright GEORG THIEME VERLAG KG |
| Palavras-Chave | #thallium(III) nitrate #carbocycles #indanes #ring contractions #oxidative rearrangements #ASYMMETRIC-SYNTHESIS #CONJUGATE ADDITION #OXIDATION #STEREOCHEMISTRY #REARRANGEMENT #ALDEHYDES #INDANONES #KETONES #NITRATE #ETHERS #Chemistry, Organic |
| Tipo |
article original article publishedVersion |
