In situ generation of n-butanethiol and its reaction with electron-deficient olefines
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
|---|---|
| Data(s) |
20/10/2012
20/10/2012
2008
|
| Resumo |
n-Butanethiol is generated in situ by sequential addition of n-butyllithium and water to elemental sulfur. The n-butanethiol formed was reacted with electron-deficient olefines to give Michael-type addition products in good yields. The method avoids the manipulation of the bad-smelling n-butanethiol. |
| Identificador |
SYNTHETIC COMMUNICATIONS, v.38, n.5, p.789-795, 2008 0039-7911 http://producao.usp.br/handle/BDPI/31363 10.1080/00397910701820897 |
| Idioma(s) |
eng |
| Publicador |
TAYLOR & FRANCIS INC |
| Relação |
Synthetic Communications |
| Direitos |
restrictedAccess Copyright TAYLOR & FRANCIS INC |
| Palavras-Chave | #Michael addition #thiols #alpha,beta-unsaturated carbonyl compound #MICHAEL ADDITION #CARBONYL-COMPOUNDS #IONIC LIQUID #THIOLS #ALKENES #HYDROTELLURATION #CATALYSIS #TELLURIUM #Chemistry, Organic |
| Tipo |
article original article publishedVersion |
