Synthesis of the C7-C24 fragment of (-)-Macrolactin F
Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
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Data(s) |
20/10/2012
20/10/2012
2008
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Resumo |
An enantioselective and convergent synthesis of the C7-C24 fragment of Macrolactin F was achieved from four main fragments. A hydrotelluration/transmetalation sequence was used to install the E,Z diene present in the molecule, while a hydrozirconation/transmetalation sequence was used to connect two advanced intermediates. (C) 2008 Elsevier Ltd. All rights reserved. Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) CNPq FACEPE FACEPE |
Identificador |
TETRAHEDRON LETTERS, v.49, n.40, p.5759-5761, 2008 0040-4039 http://producao.usp.br/handle/BDPI/31270 10.1016/j.tetlet.2008.07.113 |
Idioma(s) |
eng |
Publicador |
PERGAMON-ELSEVIER SCIENCE LTD |
Relação |
Tetrahedron Letters |
Direitos |
closedAccess Copyright PERGAMON-ELSEVIER SCIENCE LTD |
Palavras-Chave | #MARINE BACILLUS SP #MACROLACTIN-A #STEREOSELECTIVE-SYNTHESIS #ENANTIOSELECTIVE SYNTHESIS #ORGANOIRON METHODOLOGY #ASYMMETRIC-SYNTHESIS #VINYLIC TELLURIDES #C-12-C24 FRAGMENT #REAGENTS #KETONES #Chemistry, Organic |
Tipo |
article original article publishedVersion |