Mechanistic study of the addition reaction of TeCl(4) to alkynes: Participation of TeCl(3) centered-radical
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
|---|---|
| Data(s) |
20/10/2012
20/10/2012
2008
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| Resumo |
The mechanism of the addition reaction of TeCl(4) to alkynes was indirectly established by the detection of TeCl(3) centered radicals using EPR spin trapping, ESI-MS and ESI-MS/MS characterization. Crown Copyright (C) 2008 Published by Elsevier B. V. All rights reserved. Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq) FAPESP[04/13798-1] Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) |
| Identificador |
JOURNAL OF ORGANOMETALLIC CHEMISTRY, v.693, n.24, p.3558-3562, 2008 0022-328X http://producao.usp.br/handle/BDPI/31252 10.1016/j.jorganchem.2008.08.036 |
| Idioma(s) |
eng |
| Publicador |
ELSEVIER SCIENCE SA |
| Relação |
Journal of Organometallic Chemistry |
| Direitos |
restrictedAccess Copyright ELSEVIER SCIENCE SA |
| Palavras-Chave | #Tellurium #Radicals #DBNBS #EPR #Reaction mechanism #Chemistry, Inorganic & Nuclear #Chemistry, Organic |
| Tipo |
article original article publishedVersion |
