Calorimetric investigations of luminescent films polycarbonate (PC) doped with europium complex [Eu(TTA)(3)(H(2)O)(2)]

Polymers doped with rare earth complexes are advantaged in film production for many applications in the luminescent field. In this luminescent polycarbonate (PC) films doped with diaquatris(thenoyltrifluoroacetonate)europium(III) complex [Eu(TTA)(3)(H(2)O)(2)] were prepared and their calorimetric and luminescent properties in the solid state are reported. The thermal behavior was investigated by utilization of differential scanning calorimetry (DSC) and thermogravimetry (TG). Due of the addition of rare earth [Eu(TTA)(3)(H(2)O)(2)] into PC matrix, changes were observed in the thermal behavior concerning the glass transition and thermal stability. Characteristic broadened narrow bands arising from the (5)D(0) -> (7)F(J) transitions (J = 4-0) of Eu(3+) ion indicate the incorporation of the Eu(3+) ions in the polymer. The luminescent films show enhancement emission intensity with an increase of rare earth concentration in polymeric matrix accompanied by decrease in thermal stability.

IPEN/CNEN-SP (Nuclear and Energetic Research Institute, National Commission of Nuclear Energy)

IPEN/CNEN-SP (Nuclear and Energetic Research Institute, National Commission of Nuclear Energy)

Eleosmar Gasparin, Department of Fundamental Chemistry from Chemistry Institute, University of Sao Paulo (USP), Brazil

Eleosmar Gasparin, Department of Fundamental Chemistry from Chemistry Institute, University of Sao Paulo (USP), Brazil

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

CNPQ[303322/2006]