The soft nucleophilicity of organotellurolates driving the S(N)2-type lactone ring-opening reaction
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
|---|---|
| Data(s) |
20/10/2012
20/10/2012
2009
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| Resumo |
Lithium and magnesium organotellurolates were reacted with lactones producing the corresponding tellurocarboxylic acids. Treatment of the reaction mixture with lithium aluminum hydride allowed the isolation of the corresponding hydroxytellurides in a one-pot operation. (C) 2009 Published by Elsevier Ltd FAPESP Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) CNPq CAPES Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) |
| Identificador |
TETRAHEDRON LETTERS, v.50, n.47, p.6498-6501, 2009 0040-4039 http://producao.usp.br/handle/BDPI/31132 10.1016/j.tetlet.2009.09.023 |
| Idioma(s) |
eng |
| Publicador |
PERGAMON-ELSEVIER SCIENCE LTD |
| Relação |
Tetrahedron Letters |
| Direitos |
closedAccess Copyright PERGAMON-ELSEVIER SCIENCE LTD |
| Palavras-Chave | #S(N)2 lactone ring opening #Metal organochalcogenolates #Soft nucleophiles #ORGANIC-SYNTHESIS #TELLURIUM #ORGANOMETALLICS #REAGENT #ESTERS #Chemistry, Organic |
| Tipo |
article original article publishedVersion |
