Reactions of toluquinone - cyclopentadiene Diels -Alder epoxide adducts with nucleophiles under heterogeneous conditions
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
|---|---|
| Data(s) |
20/10/2012
20/10/2012
2010
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| Resumo |
Toluquinone-cyclopentadiene Diels-Alder epoxide adducts react with sulfur and oxygen nucleophiles under heterogeneous conditions, leading to products resulting from the epoxide ring opening and from skeletal rearrangement, respectively. Pyrolysis of the sulfanyl adducts gave the new 3-sulfanyltoluquinones (1). Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP) Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP) Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior (CAPES) Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq) Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) |
| Identificador |
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, v.88, n.10, p.996-1002, 2010 0008-4042 http://producao.usp.br/handle/BDPI/31029 10.1139/V10-106 |
| Idioma(s) |
eng |
| Publicador |
CANADIAN SCIENCE PUBLISHING, NRC RESEARCH PRESS |
| Relação |
Canadian Journal of Chemistry-revue Canadienne de Chimie |
| Direitos |
restrictedAccess Copyright CANADIAN SCIENCE PUBLISHING, NRC RESEARCH PRESS |
| Palavras-Chave | #toluquinone #phase-transfer catalysis (PTC) conditions #thiolation #epoxide #Diels-Alder #2,3-EPOXIDES #CHEMISTRY #QUINONES #ANALOGS #AGENTS #Chemistry, Multidisciplinary |
| Tipo |
article original article publishedVersion |
