Synthesis, characterization, and single crystal X-ray structure of the 1-furoyl-3-cyclohexylthiourea cadmium chloride complex, Cd[C4H3OC(O)NHC(S)NHC6H11]4Cl2
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
|---|---|
| Data(s) |
20/10/2012
20/10/2012
2009
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| Resumo |
Cadmium chloride complex of 1-furoyl-3-cyclohexylthiourea (CyTu) was prepared and characterized by elemental analysis, IR, and Raman spectroscopy. The structure of the complex was determined by single crystal X-ray methods (space group Bbab, a = 20.918(1), b = 23.532(1), c = 23.571(1) angstrom, = = , Z = 8). Each cadmium has distorted octahedral geometry, coordinated by two chlorides and the thiocarbonyl sulfurs from four CyTu molecules. All the spectroscopic data are consistent with coordination of CyTu by sulfur to cadmium. CNPq Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) |
| Identificador |
JOURNAL OF COORDINATION CHEMISTRY, v.62, n.17, p.2804-2813, 2009 0095-8972 http://producao.usp.br/handle/BDPI/30193 10.1080/00958970902926795 |
| Idioma(s) |
eng |
| Publicador |
TAYLOR & FRANCIS LTD |
| Relação |
Journal of Coordination Chemistry |
| Direitos |
restrictedAccess Copyright TAYLOR & FRANCIS LTD |
| Palavras-Chave | #Aroylthiourea #Cadmium(II) complexes #Synthesis #X-ray structure #NONLINEAR-OPTICAL CRYSTAL #THIOUREA #SPECTRA #METALS #RAMAN #Chemistry, Inorganic & Nuclear |
| Tipo |
article original article publishedVersion |
