Copper(II) and zinc(II) complexes with 2-formylpyridine-derived hydrazones
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
|---|---|
| Data(s) |
20/10/2012
20/10/2012
2009
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| Resumo |
In the present work 2-formylpyridine-para-chloro-phenyl hydrazone (H2FopCIPh) and 2-formylpyridine-para-nitro-phenyl hydrazone (H2FopNO(2)Ph) were obtained, as well as their copper(II) and zinc(II) complexes [Cu(H2FopClPh)Cl(2)] (1), [Cu(2FopNO(2)Ph)Cl] (2), [Zn(H2FopClPh)Cl(2)] (3) and [Zn(H2FopNO(2)Ph)Cl(2)] (4). Upon re-crystallization in DMSO:acetone conversion of 2 into [Cu(2FopNO(2)Ph)Cl(DMSO)] (2a) and of 4 into [Zn(2FopNO(2)Ph)Cl(DMSO)] (4a) occurred. The crystal structures of 1, 2a, 3 and 4a were determined. (C) 2009 Elsevier Ltd. All rights reserved. Capes Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES) Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq) CNPq (Brasil) Consejo Nacional de Investigaciones Científicas y Técnicas de Argentina (CONICET) CONICET (Argentina) |
| Identificador |
POLYHEDRON, v.28, n.17, p.3797-3803, 2009 0277-5387 http://producao.usp.br/handle/BDPI/29909 10.1016/j.poly.2009.07.059 |
| Idioma(s) |
eng |
| Publicador |
PERGAMON-ELSEVIER SCIENCE LTD |
| Relação |
Polyhedron |
| Direitos |
restrictedAccess Copyright PERGAMON-ELSEVIER SCIENCE LTD |
| Palavras-Chave | #Hydrazones #Metal complexes #Crystal structure #SPECTRAL CHARACTERIZATION #2-BENZOYLPYRIDINE-DERIVED THIOSEMICARBAZONES #MAGNETIC-INTERACTIONS #TIN(IV) COMPLEXES #DIMERS #COORDINATION #DERIVATIVES #Chemistry, Inorganic & Nuclear #Crystallography |
| Tipo |
article original article publishedVersion |
