Phase equilibria study of systems composed of refined babassu oil, lauric acid, ethanol, and water at 303.2 K
Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
---|---|
Data(s) |
19/10/2012
19/10/2012
2011
|
Resumo |
Deacidification of vegetable oils can be performed using liquid-liquid extraction as an alternative method to the classical chemical and physical refining processes. This paper reports experimental data for systems containing refined babassu oil, lauric acid, ethanol, and water at 303.2 K with different water mass fractions in the alcoholic solvent (0, 0.0557, 0.1045, 0.2029, and 0.2972). The dilution of solvent with water reduced the distribution coefficient values, which indicates a reduction in the loss of neutral oil. The experimental data were used to adjust the NRTL equation parameters. The global deviation between the observed and the estimated compositions was 0.0085, indicating that the model can accurately predict the behavior of the compounds at different levels of solvent hydration. (C) 2011 Elsevier Ltd. All rights reserved. FAPESP (Fundacao de Amparo a Pesquisa do Estado de Sao Paulo)[09/17855-3] FAPESP (Fundacao de Amparo a Pesquisa do Estado de Sao Paulo)[08/56258-8] CNPq (Conselho Nacional de Desenvolvimento Cientifico e Tecnologico) FINEP (Financiadora de Estudos e Projetos) CAPES (Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior) |
Identificador |
The Journal of Chemical Thermodynamics, v.43, n.12, p.1784-1790, 2011 0021-9614 http://producao.usp.br/handle/BDPI/26794 10.1016/j.jct.2011.05.039 |
Idioma(s) |
eng |
Publicador |
ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD |
Relação |
The Journal of Chemical Thermodynamics |
Direitos |
restrictedAccess Copyright ACADEMIC PRESS LTD- ELSEVIER SCIENCE LTD |
Palavras-Chave | #Liquid-liquid extraction #Liquid-liquid equilibrium #Experimental data #Deacidification #Solvent extraction #NRTL #LIQUID-LIQUID EQUILIBRIUM #RICE BRAN OIL #FREE FATTY-ACIDS #PLUS ETHANOL #OLEIC-ACID #SOLVENT-EXTRACTION #VEGETABLE-OILS #SOYBEAN OIL #SEED OIL #DEACIDIFICATION PROCESS #Thermodynamics #Chemistry, Physical |
Tipo |
article original article publishedVersion |