Methyl hydrazinocarboxylate as a practical alternative to hydrazine in the Wolff–Kishner reaction
| Data(s) |
01/01/2016
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| Resumo |
Herein we describe a facile protocol for the reduction of aromatic ketones and aldehydes to the corresponding methylene unit. The procedure involves isolation of a carbomethoxyhydrazone intermediate that is easily decomposed to the reduced product without the requirement for large quantities of pernicious hydrazine. |
| Formato |
text |
| Identificador |
http://centaur.reading.ac.uk/46749/1/PC%20Nov%2015%20-%20st-2015-d0771-l%20Galley%20Proof%201.pdf Cranwell, P. B. <http://centaur.reading.ac.uk/view/creators/90005600.html>, Russell, A. T. <http://centaur.reading.ac.uk/view/creators/90000368.html> and Smith, C. D. <http://centaur.reading.ac.uk/view/creators/90006042.html> (2016) Methyl hydrazinocarboxylate as a practical alternative to hydrazine in the Wolff–Kishner reaction. Synlett, 27 (1). pp. 131-135. ISSN 0936-5214 doi: 10.1055/s-0035-1560805 <http://dx.doi.org/10.1055/s-0035-1560805> |
| Idioma(s) |
en |
| Publicador |
Thieme |
| Relação |
http://centaur.reading.ac.uk/46749/ creatorInternal Cranwell, Philippa B. creatorInternal Russell, Andrew T. creatorInternal Smith, Chris D. 10.1055/s-0035-1560805 |
| Tipo |
Article PeerReviewed |
