Chemistry and structure by design: ordered CuNi(CN)4 sheets with copper(II) in a square-planar environment
| Data(s) |
09/06/2015
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| Resumo |
Layered copper–nickel cyanide, CuNi(CN)4, a 2-D negative thermal expansion material, is one of a series of copper(II)-containing cyanides derived from Ni(CN)2. In CuNi(CN)4, unlike in Ni(CN)2, the cyanide groups are ordered generating square-planar Ni(CN)4 and Cu(NC)4 units. The adoption of square-planar geometry by Cu(II) in an extended solid is very unusual. |
| Formato |
text |
| Identificador |
http://centaur.reading.ac.uk/40776/1/CuNi_dalton_1june_final.pdf Chippindale, A. M. <http://centaur.reading.ac.uk/view/creators/90000336.html>, Hibble, S. J. <http://centaur.reading.ac.uk/view/creators/90000398.html>, Marelli, E., Bilbe, E. J. <http://centaur.reading.ac.uk/view/creators/90004017.html>, Hannon, A. C. and Zbiri, M. (2015) Chemistry and structure by design: ordered CuNi(CN)4 sheets with copper(II) in a square-planar environment. Dalton Transactions, 44 (28). pp. 12502-12506. ISSN 1364-5447 doi: 10.1039/c5dt01127b <http://dx.doi.org/10.1039/c5dt01127b> |
| Idioma(s) |
en |
| Publicador |
Royal Society of Chemistry |
| Relação |
http://centaur.reading.ac.uk/40776/ creatorInternal Chippindale, A. M. creatorInternal Hibble, S. J. creatorInternal Bilbe, E. J 10.1039/c5dt01127b |
| Tipo |
Article PeerReviewed |
