Preparation and ring-opening reactions of N-diphenylphosphinyl vinyl aziridines
Data(s) |
2013
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Resumo |
Predominantly (E)-N-diphenylphosphinyl vinyl aziridines are prepared by a reaction of N-diphenylphosphinyl imines with α-bromoallyllithium in the presence of freshly fused ZnCl2. These aziridines undergo a ring-opening reaction with a variety of carbon and heteronucleophiles, in good yield, and generally with good regioselectivity. |
Formato |
text |
Identificador |
http://centaur.reading.ac.uk/32479/1/BJOC%202013%2C9%2C852.pdf Jarvis, A. N., McClaren, A. B., Osborn, H. M. I. <http://centaur.reading.ac.uk/view/creators/90000179.html> and Sweeney, J. <http://centaur.reading.ac.uk/view/creators/90000178.html> (2013) Preparation and ring-opening reactions of N-diphenylphosphinyl vinyl aziridines. Beilstein Journal of Organic Chemistry, 9. pp. 852-859. ISSN 1860-5397 doi: 10.3762/bjoc.9.98 <http://dx.doi.org/10.3762/bjoc.9.98> |
Idioma(s) |
en |
Publicador |
Beilstein-Institut |
Relação |
http://centaur.reading.ac.uk/32479/ creatorInternal Osborn, Helen M. I. creatorInternal Sweeney, Joseph 10.3762/bjoc.9.98 |
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cc_by |
Tipo |
Article PeerReviewed |