Preparation and ring-opening reactions of N-diphenylphosphinyl vinyl aziridines


Autoria(s): Jarvis, Ashley N.; McClaren, Andrew B.; Osborn, Helen M. I.; Sweeney, Joseph
Data(s)

2013

Resumo

Predominantly (E)-N-diphenylphosphinyl vinyl aziridines are prepared by a reaction of N-diphenylphosphinyl imines with α-bromoallyllithium in the presence of freshly fused ZnCl2. These aziridines undergo a ring-opening reaction with a variety of carbon and heteronucleophiles, in good yield, and generally with good regioselectivity.

Formato

text

Identificador

http://centaur.reading.ac.uk/32479/1/BJOC%202013%2C9%2C852.pdf

Jarvis, A. N., McClaren, A. B., Osborn, H. M. I. <http://centaur.reading.ac.uk/view/creators/90000179.html> and Sweeney, J. <http://centaur.reading.ac.uk/view/creators/90000178.html> (2013) Preparation and ring-opening reactions of N-diphenylphosphinyl vinyl aziridines. Beilstein Journal of Organic Chemistry, 9. pp. 852-859. ISSN 1860-5397 doi: 10.3762/bjoc.9.98 <http://dx.doi.org/10.3762/bjoc.9.98>

Idioma(s)

en

Publicador

Beilstein-Institut

Relação

http://centaur.reading.ac.uk/32479/

creatorInternal Osborn, Helen M. I.

creatorInternal Sweeney, Joseph

10.3762/bjoc.9.98

Direitos

cc_by

Tipo

Article

PeerReviewed