Evidence for the existence of multiple equilibrium states in cobalt phthalocyanine tetramer: a study by dielectric spectroscopy

In any investigation, information about the molecules under consideration is very essential for tailoring their properties. Evaluation of dispersion parameters, namely optical dielectric constant, static dielectric constant, relaxation time and spreading factor, assumes significance in this context. Dielectric spectroscopy is a useful tool for estimating these parameters. Not only does it reveal details about these constants but it also gives insight into the mechanism of conduction. In this paper the evaluation of dispersion parameters of cobalt phthalocyanine tetramer in the temperature range 300–393K is attempted using Cole–Cole plots. The temperature variation of the spreading factor indicates the existence of multiple equilibrium positions in the case of cobalt phthalocyanine tetramer. To the best of our knowledge, the evaluation of dispersion parameters for cobalt phthalocyanine tetramer is reported for the first time

J. Phys. D: Appl. Phys. 39 (2006) 1678–1683

Cochin University of Science and Technology