Synthesis, spectral and structural studies of novel binuclear Ni(II) complex of salicylaldehyde 3-azacyclothiosemicarbazone

A novel binuclear Ni(II) complex of salicylaldehyde 3-azacyclothiosemicarbazone (H2L) has been synthesized and characterized by elemental analysis, IR and UV–Vis spectroscopy. The single crystal X-ray structure of the complex shows that bridging occurs through thiolato sulfur and phenolic oxygen atoms. Nickel centers in the complex have square planar and octahedral geometries

Inorganica Chimica Acta 362 (2009) 2515–2518

Cochin University of Science and Technology