Studies On Some New Transition Metai. Complexes Of The Schiff Bases Derived From Ouinoxaline - 2 - Carboxaldehyde


Autoria(s): Mayadevi, S; Dr.Mohammed Yusuff,K K
Data(s)

29/05/2014

29/05/2014

06/08/1997

Resumo

This thesis deals with the synthesis, characterisation and catalytic activity studies of some new transition metal complexes of the Schiff bases, derived from quinoxaline—2—carboxaldehyde. The model complexes derived from specially designed and synthesised Schiff bases help us to understand the chemistry of biological systems. Schiff bases derived from heterocyclic aldehydes like quinoxaline-2-carboxaldehyde provide great structural diversity during complexation. The Schiff bases synthesised in the present study ' are quinoxaline—2—carboxa.lidene-2-aminophenol (QAP). quinoxaline—2carboxaldehyde semicarbazone (QSC), quinoxaline-2—carboxalidene—o— phenylenediamine (QOD) and quinoxaline-2-carboxalidene-2-furfurylamine (QFA). The elucidation of the structure of these complexes is done using conductance, magnetic susceptibility measurements. infrared, UV—Vis and EPR spectral studies.

Dcpanmcm of Appiied Chemistry, Cochin Univenity of science and Tochnology

Cochin Univenity of science and Tochnology

Identificador

http://dyuthi.cusat.ac.in/purl/3818

Idioma(s)

en

Publicador

Cochin University Of Science And Technology

Palavras-Chave #Reagents #Preparation of aldehyde #Preparation of ligands #QUNOXALINE-2-CARBOXALDEHYDE SEMICARBAZONE COMPLEXES , Mn(]I), Fe(1II), Co(]I), Ni(]I) AND Cu(II)
Tipo

Thesis