Photophysical and Electrochemical Investigations on Photoconducting Poly(6-tert-butyl-3,4-dihydro-2H- 1,3-benzoxazine)


Autoria(s): Sreekumar, K; Dhanya,R; Kishore,V C; Sudha Kartha, C; Rani, Joseph
Data(s)

03/12/2010

03/12/2010

2009

Resumo

Poly(6-tert-butyl-3,4-dihydro-2H-1,3-benzoxazine) was synthesized by thermally activated cationic ring opening polymerization. The structure of the polymer was confirmed by spectral and thermal studies. The highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) were estimated using cyclic voltammetry and optical absorption. Modulated photocurrent measurement technique was employed to study the spectral and field dependence of photocurrent. Photocurrent of the order of 1.5 micro A/m2 was obtained for polymer at a biasing electric field of 40 V/mico m.

Cochin University of Science and Technology

Identificador

Macromol. Symp. 2009, 277, 112–118

http://dyuthi.cusat.ac.in/xmlui/purl/1993

DOI: 10.1002/masy.200950314

Idioma(s)

en

Publicador

Wiley InterScience

Palavras-Chave #conducting polymers #fluorescence #FT-IR #glass transition #UV-vis spectroscopy
Tipo

Working Paper