Software para simulação de mecanismo de supressão da luminescência: modelo cinético de Stern-Volmer


Autoria(s): Dias Júnior,Lauro Camargo; Novo,João Batista Marques
Data(s)

01/04/2014

Resumo

A software that includes both Stochastic and Molecular Dynamics procedures has been developed with the aim of visualizing the Stern-Volmer kinetic mechanism of dynamic luminescence quenching. The software allows the student to easily simulate and graphically visualize the molecular collisions, the molecular speed distributions, the luminescence decay curves, and the Stern-Volmer graphs. The software named "SternVolmer" is written for the FreeBASIC compiler and can be applied to dynamic systems where luminescent molecules, during their excited state lifetimes, are able to collide with quenching molecules (collisional quenching). The good agreement found between the simulations and the expected results shows that this software can be used as an effective teaching aid for the study of luminescence and kinetic decay of excited states.

Formato

text/html

Identificador

http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422014000200027

Idioma(s)

pt

Publicador

Sociedade Brasileira de Química

Fonte

Química Nova v.37 n.2 2014

Palavras-Chave #Stochastic procedure #dynamic luminescence quenching mechanism #excited states decay kinetics
Tipo

journal article