Straightforward synthesis of 2,2,4,4,5,7,7-d7-cholestane: a new deuterated standard in petroleum analysis


Autoria(s): Miranda,Maicon Guerra de; Albert,Andre Luis Mazzei; Cardoso,Jari Nobrega; Lopes,Rosangela Sabbatini Capella; Lopes,Claudio Cerqueira
Data(s)

01/01/2013

Resumo

A short and efficient synthesis of heptadeuterated 2,2,4,4,5,7,7-d7-cholestane (1) from cholesterol (3) is described. The deuterated material will be useful for the analysis of different sources of petroleum in analytical geochemistry laboratories as internal standard for quantification of steranes via gas chromatography-mass spectrometry (GC-MS).

Formato

text/html

Identificador

http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422013000800014

Idioma(s)

en

Publicador

Sociedade Brasileira de Química

Fonte

Química Nova v.36 n.8 2013

Palavras-Chave #total synthesis #steroids #deuterated standard
Tipo

journal article