A comparison of electrodeposited Ti/β-PbO2 and Ti-Pt/β-PbO2 anodes in the electrochemical degradation of the direct yellow 86 dye


Autoria(s): Aquino,José M.; Irikura,Kallyni; Rocha-Filho,Romeu C.; Bocchi,Nerilso; Biaggio,Sonia R.
Data(s)

01/01/2010

Resumo

The electrochemical performance of electrodeposited Ti/β-PbO2 and Ti-Pt/β-PbO2 anodes was galvanostatically evaluated (batch mode, 50 mA cm-2) to degrade the Direct Yellow 86 dye (100 or 200 mg L-1 in 0.1 mol L-1 Na2SO4 + 1.5 g L-1 NaCl), investigating the effect of pH and temperature. Similar results were obtained for both electrodes and the best conditions for removal of color and chemical oxygen demand are pH 7 and 40 °C, when 90% decolorization is attained by passing a charge of only ~0.13 A h L-1 and total mineralization is achieved with expenditure of ~5 kW h m-3.

Formato

text/html

Identificador

http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422010001000023

Idioma(s)

en

Publicador

Sociedade Brasileira de Química

Fonte

Química Nova v.33 n.10 2010

Palavras-Chave #PbO2 anode #electrochemical degradation of wastewater #indirect oxidation
Tipo

journal article