Desidratação de etanol sobre material nanoestruturado do tipo LaSBA-15


Autoria(s): Luz Jr,Geraldo E.; Melo,Ana C. R.; Lima,Stevie H.; Araujo,Antônio S.; Fernandes Jr.,Valter J.
Data(s)

01/01/2010

Resumo

La-incorporated SBA-15 mesopourous molecular sieves (LaSBA-15) were directly synthesized with aim to convert ethanol to ethylene. The samples were characterized by XRD, XRF, nitrogen sorption and acidity, by thermodesorption of n-buthylamine. The results have indicated that all the samples have showed high ordered mesostructure with a large average pore size, and that the lanthanum incorporation has caused an increase in the acidity of the SBA-15. The LaSBA-15 samples have improved, with low deactivation rate, the conversion of the ethanol to water, ether, acetaldehyde and ethylene. In addition, they have increased the ethylene selectivity.

Formato

text/html

Identificador

http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422010000800005

Idioma(s)

pt

Publicador

Sociedade Brasileira de Química

Fonte

Química Nova v.33 n.8 2010

Palavras-Chave #ethanol dehydration #LaSBA-15 #ethylene
Tipo

journal article