Aplicação de α-oxoceteno ditiocetais em síntese orgânica


Autoria(s): Siqueira,Geonir M.; Neuenfeldt,Patrícia D.; Duarte,Anaí; Bretanha,Lizandra C.; Freitag,Rogério A.; Cunico,Wilson
Data(s)

01/01/2010

Resumo

The synthesis and reactivity of α-oxoketenes dithioacetals (S,S-acetals), general structure [(R¹C=OC(R²)=C(SR³)(SR4)], are reported. We also showed the application of S,S acetals as synthons for efficient synthesis of isoxazoles, pyrazoles, indazoles, thiophenes, dithiol thiones, pyridines, pyrimidines and other heterocycles. This work aims to review the importance of α-oxoketenes dithioacetals in organic chemistry during the past few years.

Formato

text/html

Identificador

http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422010000300039

Idioma(s)

pt

Publicador

Sociedade Brasileira de Química

Fonte

Química Nova v.33 n.3 2010

Palavras-Chave #S,S-acetals #heterocycles #α-oxoketene dithioacetals
Tipo

journal article