Estudo da adsorção de brometo de etídeo em resina XAD-7


Autoria(s): Oliveira,Mônica Winkler de; Hilsdorf,Alexandre W. S.; Silva,Astréa F. de Souza; Oliveira,André Fernando
Data(s)

01/01/2009

Resumo

The adsorption of ethidium bromide on XAD-7 resin was studied. The Freundlich model was the most representative isotherm model to describe the sorption behavior. A solid-liquid equilibrium model was proposed to explain the resin mass influence on the sorption. The equilibrium constant value estimated was 2.31. The results showed an ethidium bromide ion-pair physical adsorption, with adsorption enthalpy equals to -19.33 kJ/mol. A pK2 value equals to 4.69 ± 0.01 was estimated by two distinct methods. The results will be applied to the ethidium bromide preconcentration aiming its decomposition.

Formato

text/html

Identificador

http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422009000500010

Idioma(s)

pt

Publicador

Sociedade Brasileira de Química

Fonte

Química Nova v.32 n.5 2009

Palavras-Chave #ethidium bromide #XAD-7 resin #adsorption isotherm
Tipo

journal article