Alargamento da distribuição de massa molar de polímeros sintetizados com catalisadores metalocênicos dual-site


Autoria(s): Santos,João H. Z. dos; Fisch,Adriano G.; Cardozo,Nilo S. M.; Secchi,Argimiro R.
Data(s)

01/01/2008

Resumo

The main topics related to the use of dual-site catalysts in the production of polymers with broad molecular weight distribution are reviewed. The polymerization using dual-site catalysts is more economical and allows to produce a higher quality product than other processes, such as polymer blend and multistage reactors. However, the formulation of these catalysts is quite complicated since the same catalyst must produce distinct polymer grades. In addition, the release of patents concerning the combination of metallocenes and new technologies for polymerization shows that polymerization processes using dual-site catalysts are of current industrial interest.

Formato

text/html

Identificador

http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422008000500049

Idioma(s)

pt

Publicador

Sociedade Brasileira de Química

Fonte

Química Nova v.31 n.5 2008

Palavras-Chave #metallocene #dual-site #molecular weight distribution
Tipo

journal article