Cânfora: um bom modelo para ilustrar técnicas de RMN


Autoria(s): Yoneda,Julliane Diniz; Leal,Kátia Zaccur; Seidl,Peter Rudolf; Azeredo,Rodrigo Bagueira de V.; Kleinpeter,Erich
Data(s)

01/01/2007

Resumo

The use of Nuclear Magnetic Resonance spectroscopy to establish the three-dimensional structures of molecules is an important component of modern Chemistry courses. The combination of techniques that can be used for this purpose is conveniently illustrated by their application to the camphor molecule. This paper presents applications of several techniques used in NMR spectral interpretation in an increasing order of complexity. The result of individual experiments is illustrated in order to familiarize the user with the way connectivity through bonds and through space is established from 1D/2D-NMR spectra and molecular stereochemistry is determined from different NMR experiments.

Formato

text/html

Identificador

http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422007000800043

Idioma(s)

pt

Publicador

Sociedade Brasileira de Química

Fonte

Química Nova v.30 n.8 2007

Palavras-Chave #organic chemistry #NMR spectroscopy #camphor
Tipo

journal article