TitGer: uma planilha eletrônica para simulação de titulação de mistura de compostos polipróticos


Autoria(s): Oliveira,André Fernando; Silva,Astréa F. de Souza; Tenan,Mário A.; Olivo,Sérgio Lineu
Data(s)

01/02/2007

Resumo

The aim of this paper is to present a simple way of treating the general equation for acid-base titrations based on the concept of degree of dissociation, and to propose a new spreadsheet approach for simulating the titration of mixtures of polyprotic compounds. The general expression, without any approximation, is calculated a simple iteration method, making number manipulation easy and painless. The user-friendly spreadsheet was developed by using MS-Excel and Visual-Basic-for-Excel. Several graphs are drawn for helping visualizing the titration behavior. A Monte Carlo function for error simulation was also implemented. Two examples for titration of alkalinity and McIlvaine buffer are presented.

Formato

text/html

Identificador

http://www.scielo.br/scielo.php?script=sci_arttext&pid=S0100-40422007000100036

Idioma(s)

pt

Publicador

Sociedade Brasileira de Química

Fonte

Química Nova v.30 n.1 2007

Palavras-Chave #titration simulation #mixture of polyprotic species #acid-base titration
Tipo

journal article