Total synthesis of (-)-isoavenaciolide
Contribuinte(s) |
Universitat de Barcelona |
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Resumo |
An enantioselective approach to (-)-isoavenaciolide was achieved starting from 1- undecyn-3-ol. The synthesis relied upon the preparation of a chiral 4-silyloxy-2-alkenylborane by hydroboration of a protected 2,3-allenol and subsequent stereoselective addition to 2- thiophenecarboxaldehyde |
Identificador | |
Idioma(s) |
eng |
Publicador |
American Chemical Society |
Direitos |
(c) American Chemical Society , 2013 info:eu-repo/semantics/openAccess |
Palavras-Chave | #Biomolècules #Productes naturals #Síntesi asimètrica #Medicaments antibacterians #Fungicides #Biomolecules #Natural products #Asymmetric synthesis #Antibacterial agents #Fungicides |
Tipo |
info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion |