First enantioselective synthesis of isagarin, a natural product isolated from Pentas longiflora Oliv.
| Contribuinte(s) |
Universitat de Barcelona |
|---|---|
| Data(s) |
13/06/2014
|
| Resumo |
For the first time, an enantioselective synthesis of both 1R,4S-isagarin 1a and 1S,4R-isagarin 1b was achieved starting from 1,4-dimethoxy-2-vinylnaphtalene 2. The key steps involve a Sharpless asymmetric dihydroxylation and reaction with an acetonylating pyridinium ylid. |
| Identificador | |
| Idioma(s) |
eng |
| Publicador |
Elsevier B.V. |
| Direitos |
(c) Elsevier B.V., 2010 info:eu-repo/semantics/openAccess |
| Palavras-Chave | #Síntesi asimètrica #Productes naturals #Asymmetric synthesis #Natural products |
| Tipo |
info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion |
