Pauson-Khand reaction of internal dissymmetric trifluoromethyl alkynes. influence of the alkene on the regioselectivity
| Data(s) |
23/05/2014
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| Resumo |
Abstract: The scope of the Pauson-Khand reaction (PKR) of internal trifluoromethyl alkynes, previously described with norbornadiene, is expanded to norbornene and ethylene. A thorough structural analysis of the resulting PK adducts has been carried out to unveil that α-trifluoromethylcyclopentenones are preferred in all cases, independently of the electronic properties of the alkyne. The regioselectivity observed with norbornadiene and ethylene is higher than in the case of norbornene. |
| Identificador | |
| Idioma(s) |
eng |
| Publicador |
MDPI Publishing |
| Direitos |
cc-by (c) Aiguabella Font, Núria et al., 2014 http://creativecommons.org/licenses/by/3.0/es info:eu-repo/semantics/openAccess |
| Palavras-Chave | #Ciclització (Química) #Química organometàl·lica #Cobalt #Ring formation (Chemistry) #Organometallic chemistry #Cobalt |
| Tipo |
info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion |
