Stereoselective Acetate Aldol Reactions From Metal Enolates


Autoria(s): Ariza Piquer, Xavier; García Gómez, Jordi; Romea, Pedro; Urpí Tubella, Fèlix
Data(s)

03/04/2014

Resumo

This review deals with metal enolate-mediated stereoselective acetate aldol reactions. It summarizes recent advances on aldol additions of unsubstituted metal enolates from chiral auxiliaries, stoichiometric and catalytic Lewis acids, or acting in substrate- controlled reactions, which provide stereocontrolled aldol transformations that allow the efficient synthesis of structurally complex natural products.

Identificador

http://hdl.handle.net/2072/227669

Idioma(s)

eng

Publicador

Georg Thieme Verlag

Direitos

(c) Georg Thieme Verlag, 2011

info:eu-repo/semantics/openAccess

Palavras-Chave #Reacció aldòlica #Productes naturals #Quiralitat #Catàlisi #Aldol reaction #Natural products #Chirality #Catalysis
Tipo

info:eu-repo/semantics/article

info:eu-repo/semantics/acceptedVersion