Enantioselective formal synthesis of ent-rhynchophylline and ent-isorhynchophylline
| Data(s) |
08/03/2014
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|---|---|
| Resumo |
Starting from (S)-tryptophanol, a formal synthesis of ent-rhyncho-phylline and ent-isorhynchophylline, involving stereoselective cyclocondensation, spirocyclization, and alkylation reactions, and the final adjustment of the oxidation level at the oxindole and piperidine moieties, is reported. |
| Identificador | |
| Idioma(s) |
eng |
| Publicador |
Royal Society of Chemistry |
| Direitos |
(c) Amat Tusón, Mercedes et al., 2013 info:eu-repo/semantics/openAccess |
| Palavras-Chave | #Alcaloides #Síntesi asimètrica #Estereoquímica #Alkaloids #Asymmetric synthesis #Stereochemistry |
| Tipo |
info:eu-repo/semantics/article info:eu-repo/semantics/acceptedVersion |
