Characterization of surface functional groups present on laboratory-generated and ambient aerosol particles by means of heterogeneous titration reactions


Autoria(s): Setyan Ari; Sauvain Jean-Jacques; Riediker Michael; Guillemin Michel; Rossi Michel J.
Data(s)

2009

Resumo

A Knudsen flow reactor has been used to quantify surface functional groups on aerosols collected in the field. This technique is based on a heterogeneous titration reaction between a probe gas and a specific functional group on the particle surface. In the first part of this work, the reactivity of different probe gases on laboratory-generated aerosols (limonene SOA, Pb(NO3)2, Cd(NO3)2) and diesel reference soot (SRM 2975) has been studied. Five probe gases have been selected for the quantitative determination of important functional groups: N(CH3)3 (for the titration of acidic sites), NH2OH (for carbonyl functions), CF3COOH and HCl (for basic sites of different strength), and O3 (for oxidizable groups). The second part describes a field campaign that has been undertaken in several bus depots in Switzerland, where ambient fine and ultrafine particles were collected on suitable filters and quantitatively investigated using the Knudsen flow reactor. Results point to important differences in the surface reactivity of ambient particles, depending on the sampling site and season. The particle surface appears to be multi-functional, with the simultaneous presence of antagonistic functional groups which do not undergo internal chemical reactions, such as acid-base neutralization. Results also indicate that the surface of ambient particles was characterized by a high density of carbonyl functions (reactivity towards NH2OH probe in the range 0.26-6 formal molecular monolayers) and a low density of acidic sites (reactivity towards N(CH3)3 probe in the range 0.01-0.20 formal molecular monolayer). Kinetic parameters point to fast redox reactions (uptake coefficient ?0>10-3 for O3 probe) and slow acid-base reactions (?0<10-4 for N(CH3)3 probe) on the particle surface. [Authors]

Identificador

http://serval.unil.ch/?id=serval:BIB_B477DBDA9F10

isbn:0021-8502

doi:10.1016/j.jaerosci.2009.01.008

isiid:000267327700006

http://my.unil.ch/serval/document/BIB_B477DBDA9F10.pdf

http://nbn-resolving.org/urn/resolver.pl?urn=urn:nbn:ch:serval-BIB_B477DBDA9F105

Idioma(s)

en

Direitos

info:eu-repo/semantics/openAccess

Fonte

Journal of Aerosol Science, vol. 40, no. 6, pp. 534-548

Palavras-Chave #Vehicle Emissions ; Aerosols ; Particulate Matter ; Oxidative Stress ; Reactive Oxygen Species ; Biological Markers ; Surface Properties ; Occupational Exposure
Tipo

info:eu-repo/semantics/article

article