Baeyer-Villiger oxidation of Keotones catalysed by rhenium complexes bearing N- Or Oxo-Ligands
| Data(s) |
08/09/2015
08/09/2015
07/11/2012
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| Resumo |
Rhenium (I, III-V or VII) complexes bearing N-donor or oxo-ligands catalyse the Baeyer-Villiger oxidation of cyclic and linear ketones (e.g. 2-methylcyclohexanone, 2-methylcyclopentanone, cyclohexanone, cyclopentanone, cyclobutanone and 3,3-dimethyl-2-butanone) into the corresponding lactones or esters, in the presence of aqueous H2O2 (30%). The effects of various reaction parameters are studied allowing to achieve yields up to 54%. |
| Identificador |
Alegria, E. C. B. A.; [et al] – Baeyer-Villiger oxidation of Keotones catalysed by rhenium complexes bearing N- Or Oxo-Ligands. Applied Catalysis A-General. ISSN: 0926-860X. Vol. 443 (2012), pp. 27-32 0926-860X http://hdl.handle.net/10400.21/5095 10.1016/j.apcata.2012.07.007 |
| Idioma(s) |
eng |
| Publicador |
Elsevier Science BV |
| Relação |
Fundação para a Ciência e a Tecnologia - PTDC/QUIQUI/102150/2008 Fundação para a Ciência e a Tecnologia - PTDC-EQU-EQU-122025-2010 Fundação para a Ciência e a Tecnologia - PEst-OE/QUI/U10100/2011 |
| Direitos |
closedAccess |
| Palavras-Chave | #Baeyer-Villiger Oxidation #Hydrogen Peroxide #Rhenium Complexes #Homogeneous Catalysis #Ketones #Lactones #C-Scorpionates #Pyrazole #PT-II catalysts #Hydrogen-peroxide #Molecular-oxygen #Ionic liquids #Lactone hydrolysis #Metal-catalysts #Lewis acidity #Platinum(II) #Palladium(II) #Cyclohexanone |
| Tipo |
article |
