A fluorescente bicyclic Calix[4] Arene-Oxacyclophane with planar chirality: Resolution, chiroptical, properties, and absolute configuration.
| Data(s) |
24/08/2015
24/08/2015
15/04/2014
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| Resumo |
A new inherently chiral calix[4]arene ICC 1 has been disclosed. The dissymmetry of 1 is generated from a chirality plane in the quinol moiety of a 1,3-bridged bicyclic calix[4]arene. ICC 1 has been resolved by enantioselective HPLC, and the chiroptical properties of both isolated antipodes (pS)-1 and (pR)-1 confirm their enantiomeric nature. The absolute configuration of the (pS)-1/(pR)-1 enantiomeric pair was established through time-dependent density functional theory (TDDFT) calculations of electronic circular dichroism (CD) spectra. (C) 2014 Elsevier Ltd. All rights reserved. |
| Identificador |
PRATA, José Virgílio Coelho; [et al] – A fluorescente bicyclic Calix[4] Arene-Oxacyclophane with planar chirality: Resolution, chiroptical, properties, and absolute configuration. Tetrahedron-Asymmetry. ISSN: 0957-4166. Vol. 25, nr. 6-7 (2014), pp. 547-553 0957-4166 http://hdl.handle.net/10400.21/4920 10.1016/j.tetasy.2014.02.012 |
| Idioma(s) |
eng |
| Publicador |
Pergamon-Elsevier Science LTD |
| Relação |
http://www.sciencedirect.com/science/article/pii/S0957416614000925# |
| Direitos |
closedAccess |
| Palavras-Chave | #Ray Molecular-Structures #Calixarenes |
| Tipo |
article |
