Homogeneous and heterogenised new gold C-scorpionate complexes as catalysts for cyclohexane oxidation
| Data(s) |
08/11/2013
08/11/2013
2013
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|---|---|
| Resumo |
Gold(III) complexes of type [AuCl2{eta(2)-RC(R'pz)(3)}]Cl [R = R' = H (1), R = CH2OH, R' = H (2) and R = H, R' = 3,5-Me-2(3), pz = pyrazol-1-yl] were supported on carbon materials (activated carbon, carbon xerogel and carbon nanotubes) and used for the oxidation of cyclohexane to cyclohexanol and cyclohexanone, with aqueous H2O2, under mild conditions. |
| Identificador |
ALMEIDA, M. Peixoto de; MARTINS, L. M. D. R. S.; CARABINEIRO, S. A. C. ; LAUTERBACH, T. ; ROMINGER, F.; HASHMI, A. S. K.; POMBEIRO, A. J. L.; FIGUEIREDO, J. L. - Homogeneous and heterogenised new gold C-scorpionate complexes as catalysts for cyclohexane oxidation. Catalysis Science & Technology. ISSN 2044-4753. Vol. 3, nr. 11 (2013), p. 3056-3069. 2044-4753 10.1039/c3cy00552f |
| Idioma(s) |
eng |
| Publicador |
Royal Soc Chemistry |
| Direitos |
restrictedAccess |
| Palavras-Chave | #Schiff-base complex #Manganese(III) Salen complexes #Ray-Absorption spectroscopy #Wall carbon nanotubes #Peroxidative oxidation #Activated carbon #Hydrogen-Peroxide #Coordination-compounds #Gold(III) complexes #Rhenium complexes |
| Tipo |
article |
