A Hexanuclear Mixed-Valence Oxovanadium(IV,V) Complex as a Highly Efficient Alkane Oxidation Catalyst
| Data(s) |
17/10/2013
17/10/2013
05/11/2012
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| Resumo |
The new hexanuclear mixed-valence vanadium complex [V3O3(OEt)(ashz)(2)(mu-OEt)](2) (1) with an N,O-donor ligand is reported. It acts as a highly efficient catalyst toward alkane oxidations by aqueous H2O2. Remarkably, high turnover numbers up to 25000 with product yields of up to 27% (based on alkane) stand for one of the most active systems for such reactions. |
| Identificador |
SUTRADHAR, Manas; KIRILLOVA, Marina V.; SILVA, M. Fátima C. Guedes da; MARTINS, Luísa M. D. R. S.; POMBEIRO, Armando J. L. - A Hexanuclear Mixed-Valence Oxovanadium(IV,V) Complex as a Highly Efficient Alkane Oxidation Catalyst. Inorganic Chemistry. ISSN: 0020-1669. Vol. 51, nr 21, (2012), p. 11229-11231. 0020-1669 10.1021/ic3017062 |
| Idioma(s) |
eng |
| Publicador |
Amer Chemical Soc |
| Direitos |
restrictedAccess |
| Palavras-Chave | #Hydrocarbon Oxygenations #Vanadium Complexes #Crystal-Structure #Solid-State #Ligand #2-Naphtols #Compound #Core #DFT |
| Tipo |
article |
