A dramatic effect of double bond configuration in N-oxy-3-aza Cope rearrangements: a simple synthesis of functionalised allenes
| Data(s) |
06/01/2012
06/01/2012
01/03/2009
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|---|---|
| Resumo |
The first examples of low temperature N-oxy-3-aza Cope rearrangements, leading to functionalised allenes are described, where the Z-configuration of the enaminic double bond in the rearranging system proves critical. |
| Identificador |
Pinto L, Glória P, Gomes M, Rzepa HS, Prabhakar S, Lobo AM. A dramatic effect of double bond configuration in N-oxy-3-aza Cope rearrangements: a simple synthesis of functionalised allenes. Tetrahedron Lett. 2009;50:3446-9. 0040-4039 |
| Idioma(s) |
eng |
| Publicador |
Elsevier |
| Relação |
http://www.sciencedirect.com/science/article/pii/S0040403909005115 |
| Direitos |
restrictedAccess |
| Palavras-Chave | #Chemistry #3-Aza Cope Rearrangements #Hydroxylamines #Enamines #Allenes #Configuration #Intermediates #Transition states |
| Tipo |
article |
