SbCl5—wet acetonitrile: a new system for chemoselective O-desilylation
| Data(s) |
04/01/2012
04/01/2012
2003
|
|---|---|
| Resumo |
Abstract—A new efficient method for deprotection of TBDMS derivatives of phenols, primary alcohols, carboxylic acids and secondary amines, consisting of SbCl5 and MeCN with 0.1% water (w/v), is reported. It effects inter alia desilylation of a CH2OTBDMS group in the presence of a ketal function. |
| Identificador |
Glória PM, Prabhakar S, Lobo AM, Gomes M. SbCl5—wet acetonitrile: a new system for chemoselective O-desilylation. Tetrahedron Lett. 2003;44:8819-21. 0040-4039 |
| Idioma(s) |
eng |
| Publicador |
Pergamon |
| Relação |
http://144.206.159.178/FT/1010/201970/5118247.pdf |
| Direitos |
openAccess |
| Palavras-Chave | #Química #TBDMS |
| Tipo |
article |
