Bridgehead arylation: A direct route to advanced intermediates for the synthesis of C-20 diterpene alkaloids


Autoria(s): Williams, C. M.; Mander, L. N.
Data(s)

01/01/2003

Resumo

[GRAPHICS] Rapid access to the ABCE ring system of the C-20 diterpene alkaloids was achieved by silver(I)-promoted intramolecular Friedel-Crafts arylation of a functional group-specific 5-bromo-3-azabicyclo[3.3.1]nonane derivative.

Identificador

http://espace.library.uq.edu.au/view/UQ:66147

Idioma(s)

eng

Publicador

American Chemical Society

Palavras-Chave #Chemistry, Organic #Double Michael Reaction #Aconite Alkaloids #Hetisine-type #Methyllycaconitine #Ring #Rearrangement #Conversion #Oxidation #Analogs #Imide #C1 #250301 Organic Chemical Synthesis #780103 Chemical sciences
Tipo

Journal Article