Bridgehead arylation: A direct route to advanced intermediates for the synthesis of C-20 diterpene alkaloids
| Data(s) |
01/01/2003
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| Resumo |
[GRAPHICS] Rapid access to the ABCE ring system of the C-20 diterpene alkaloids was achieved by silver(I)-promoted intramolecular Friedel-Crafts arylation of a functional group-specific 5-bromo-3-azabicyclo[3.3.1]nonane derivative. |
| Identificador | |
| Idioma(s) |
eng |
| Publicador |
American Chemical Society |
| Palavras-Chave | #Chemistry, Organic #Double Michael Reaction #Aconite Alkaloids #Hetisine-type #Methyllycaconitine #Ring #Rearrangement #Conversion #Oxidation #Analogs #Imide #C1 #250301 Organic Chemical Synthesis #780103 Chemical sciences |
| Tipo |
Journal Article |