Methoxy(2-pyridyl)ketene
| Data(s) |
01/01/2003
|
|---|---|
| Resumo |
Matrix photolysis of 3-methoxycarbonyl-1,2,3-triazolo[1,5-a]pyridine (12) affords s-E-2-pyridylketene (4), but flash vacuum thermolysis of 12 gives methoxy(2-pyridyl)ketene (15), predominantly in the s-Z-conformation. Matrix photolysis of 15 affords 2-acetylpyridine. Copyright (C) 2003 John Wiley Sons, Ltd. |
| Identificador | |
| Idioma(s) |
eng |
| Publicador |
John Wiley |
| Palavras-Chave | #Chemistry, Organic #Chemistry, Physical #Ketenes #Carbenes #Matrix Isolation #Photolysis #Flash Vacuum Thermolysis #Wolff Rearrangement #Spectroscopy #C1 #250303 Physical Organic Chemistry #780103 Chemical sciences |
| Tipo |
Journal Article |
