Magnetic Investigation of CoFe(2)O(4) Nanoparticles Supported in Biocompatible Polymeric Microsphere


Autoria(s): COAQUIRA, J. A. H.; VACCARI, C. B.; TEDESCO, A. C.; MORAIS, P. C.
Contribuinte(s)

UNIVERSIDADE DE SÃO PAULO

Data(s)

19/10/2012

19/10/2012

2009

Resumo

Magnetic investigation of spinel ferrite nanoparticles dispersed in biocompatible polymeric microspheres is reported in this study. X-ray diffraction data analysis confirms the presence of nanosized CoFe(2)O(4) particles (mean size of similar to 8 nm). This finding is corroborated by transmission electron microscopy micrographs. Magnetization isotherms suggest a spin disorder likely occurring at the nanoparticle`s surface. The saturation magnetization value is used to estimate particle concentration of 1.6 x 10(18) cm(-3) dispersed in the polymeric template. A T(1/2) dependence of the coercive field is determined in the low-temperature region (T < 30 K). The model of non-interacting mono-domains is used to estimate an effective magnetic anisotropy of K(eff) = 0.6 x 10(5) J/m(3). The K(eff) value we found is lower than the value reported for spherically-shaped CoFe(2)O(4) nanoparticles, though consistent with the low coercive field observed in the investigated sample.

Identificador

IEEE TRANSACTIONS ON MAGNETICS, v.45, n.10, Special Issue, p.4059-4062, 2009

0018-9464

http://producao.usp.br/handle/BDPI/20860

10.1109/TMAG.2009.2026291

http://dx.doi.org/10.1109/TMAG.2009.2026291

Idioma(s)

eng

Publicador

IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC

Relação

Ieee Transactions on Magnetics

Direitos

restrictedAccess

Copyright IEEE-INST ELECTRICAL ELECTRONICS ENGINEERS INC

Palavras-Chave #Magnetic coercive field #magnetization isotherm #polymer dispersed CoFe(2)O(4) nanoparticles #thermal blocking process #magnetic fluid #DIVINYLBENZENE MESOPOROUS TEMPLATE #SUSCEPTIBILITY #PARTICLES #RESONANCE #Engineering, Electrical & Electronic #Physics, Applied
Tipo

article

proceedings paper

publishedVersion