Synthesis of (Z)-1-Organylthiobut-1-en-3-ynes: Hydrothiolation of Symmetrical and Unsymmetrical Buta-1,3-diynes
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
|---|---|
| Data(s) |
19/10/2012
19/10/2012
2009
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| Resumo |
Hydrothiolation of 1-organylbuta-1,3-diynes and 1,4-diorganylbuta-1,3-diynes with the sodium organylthiolate anions, which were generated in situ by reacting diphenyl and dibutyl disulfide with NaBH(4) in ethanol, results in the regio-, stereo-, and chemoselective formation of (Z)-1-organylthio-4-organylbut-1-en-3-ynes and (Z)-1-organylthio-1,4-diorganylbut-1-en-3-ynes, respectively. FAPESP FUNDECT-MS FAPERGS PROPP-UFMS CNPq |
| Identificador |
SYNLETT, n.6, p.986-990, 2009 0936-5214 http://producao.usp.br/handle/BDPI/20708 10.1055/s-0028-1088196 |
| Idioma(s) |
eng |
| Publicador |
GEORG THIEME VERLAG KG |
| Relação |
Synlett |
| Direitos |
restrictedAccess Copyright GEORG THIEME VERLAG KG |
| Palavras-Chave | #hydrothiolation #organylthiolate anion #vinyl sulfides #1,3-diacetylenes #(Z)-1-organylthiobut-1-en-3-ynes #ALKYL PHENYL SULFIDES #ACYL ANION EQUIVALENTS #RADICAL-ADDITION #VINYL SULFIDES #ALKYLLITHIUM REAGENTS #PARA-TOLUENETHIOL #CARBOXYLIC-ACIDS #ENOL THIOETHERS #ALPHA-OLEFINS #SEQUENCE #Chemistry, Organic |
| Tipo |
article original article publishedVersion |
