Cyclopropyl fatty acids implicate a radical but not a cation as an intermediate in P450(BM3)-catalysed hydroxylations
| Data(s) |
07/03/2004
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|---|---|
| Resumo |
Novel cyclopropyl containing fatty acids are good substrates for P450(BM3) catalysed hydroxylation and analysis of their oxidation products indicates the presence of a radical intermediate (maximum rebound rate 2.6x10(10) s(-1)) and the absence of any cationic intermediate. |
| Identificador | |
| Idioma(s) |
eng |
| Publicador |
Royal Society of Chemistry |
| Palavras-Chave | #Chemistry, Multidisciplinary #2-state Reactivity #Cytochrome-p-450 #Mechanisms #Norcarane #Clocks #Probes #Step #03 Chemical Sciences #06 Biological Sciences |
| Tipo |
Journal Article |
