Synthesis of symmetrical 1,3-diynes via homocoupling reaction of n-butyl alkynyltellurides
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
|---|---|
| Data(s) |
19/10/2012
19/10/2012
2009
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| Resumo |
An ultrasound-assisted synthesis of symmetrical 1,3-diyne compounds with electron-withdrawing or donating substituents is described and illustrated by the palladium-catalyzed homocoupling reaction of n-butyl alkynyltellurides. This procedure offers easy access to 1,3-diynes in very short reaction times, and the products are achieved in good to excellent yields. (C) 2009 Elsevier Ltd. All rights reserved. CNPq[300613/2007-5] FAPESP[07/59404-2] FAPESP[07/51466-9] |
| Identificador |
TETRAHEDRON LETTERS, v.50, n.22, p.2636-2639, 2009 0040-4039 http://producao.usp.br/handle/BDPI/20417 10.1016/j.tetlet.2009.03.078 |
| Idioma(s) |
eng |
| Publicador |
PERGAMON-ELSEVIER SCIENCE LTD |
| Relação |
Tetrahedron Letters |
| Direitos |
closedAccess Copyright PERGAMON-ELSEVIER SCIENCE LTD |
| Palavras-Chave | #Homocoupling reaction #Symmetrical 1,3-diynes #Alkynyltellurides #CROSS-COUPLING REACTION #ARYL GRIGNARD-REAGENTS #TERMINAL ALKYNES #ORGANOMAGNESIUM COMPOUNDS #EFFICIENT SYNTHESIS #ORGANIC TELLURIDES #LIQUID-CRYSTALS #BETA-HYDROGENS #CHEMISTRY #HALIDES #Chemistry, Organic |
| Tipo |
article original article publishedVersion |
