Photochemical cleavage of nitrate ion coordinated to a Cr(III) porphyrin#
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
|---|---|
| Data(s) |
19/10/2012
19/10/2012
2010
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| Resumo |
Photolysis of the nitrato chromium(III) tetraphenylporphyrinato compound Cr(TPP)(NO(3)) (TPP, tetraphenylporphyrin) in toluene solution clearly leads to the formation of the Cr(IV) oxo complex Cr(TPP)(O) with a quantum yield of 0.011. The other product, NO(2), was detected quantitatively by its reaction with the spin trapping agent 2,2,6,6-tetramethyl-piperidine-1-oxyl. US National Science Foundation (NSF)[CHE-0352650] US National Science Foundation (NSF)[CHE-0749524] UCSB Office of Undergraduate Research, URCA |
| Identificador |
JOURNAL OF COORDINATION CHEMISTRY, v.63, n.14-16, p.2743-2749, 2010 0095-8972 http://producao.usp.br/handle/BDPI/20015 10.1080/00958972.2010.492217 |
| Idioma(s) |
eng |
| Publicador |
TAYLOR & FRANCIS LTD |
| Relação |
Journal of Coordination Chemistry |
| Direitos |
restrictedAccess Copyright TAYLOR & FRANCIS LTD |
| Palavras-Chave | #Chromium(III) #Photochemistry #Nitrite #Nitrogen dioxide #NITRIC-OXIDE GENERATION #NITROGEN-DIOXIDE #NITROSYL COMPLEX #NO #DELIVERY #LIGHT #TRANS-CR(CYCLAM)(ONO)(2)(+) #TETRAPHENYLPORPHYRIN #MECHANISM #Chemistry, Inorganic & Nuclear |
| Tipo |
article original article publishedVersion |
