Probing the electronic delocalization in a cyclic pyrazine ruthenium cluster hexamer
| Contribuinte(s) |
UNIVERSIDADE DE SÃO PAULO |
|---|---|
| Data(s) |
19/10/2012
19/10/2012
2010
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| Resumo |
[Ru(3)O(CH(3)COO)(6)(pz)(CO)](6) is a cyclic hexamer species encompassing six triangular ruthenium cluster centers bridged by pyrazine ligands. The electronic communication among the cluster units strongly depends on their oxidation states, and has been successfully probed by means of cyclic voltammetry and UV-vis spectroelectrochemistry. (C) 2010 Elsevier B.V. All rights reserved. FAPESP CNPq |
| Identificador |
INORGANIC CHEMISTRY COMMUNICATIONS, v.13, n.9, p.1032-1035, 2010 1387-7003 http://producao.usp.br/handle/BDPI/19996 10.1016/j.inoche.2010.06.003 |
| Idioma(s) |
eng |
| Publicador |
ELSEVIER SCIENCE BV |
| Relação |
Inorganic Chemistry Communications |
| Direitos |
restrictedAccess Copyright ELSEVIER SCIENCE BV |
| Palavras-Chave | #Ruthenium clusters #Electrochemistry #Spectroeletrochemistry #Cyclic cluster #Molecular modeling #TRIRUTHENIUM CLUSTER #REDOX PROPERTIES #BEHAVIOR #DIMERS #Chemistry, Inorganic & Nuclear |
| Tipo |
article original article publishedVersion |
