One-step biomimetic conversion of a furanoheliangolide into an eremantholide using Stryker`s reagent


Autoria(s): SASS, Daiane Cristina; HELENO, Vladimir Constantino Gomes; LOPES, Joao Luis Callegari; CONSTANTINO, Mauricio Gomes
Contribuinte(s)

UNIVERSIDADE DE SÃO PAULO

Data(s)

19/10/2012

19/10/2012

2008

Resumo

The conversion of a furanoheliangolide structure (15-deoxygoyazensolide) into an eremantholide one (eremantholide C) was achieved by tandem hydride conjugate addition-intramolecular carbanion addition using Stryker`s reagent. (c) 2008 Elsevier Ltd. All rights reserved.

Identificador

TETRAHEDRON LETTERS, v.49, n.24, p.3877-3880, 2008

0040-4039

http://producao.usp.br/handle/BDPI/19939

10.1016/j.tetlet.2008.04.071

http://dx.doi.org/10.1016/j.tetlet.2008.04.071

Idioma(s)

eng

Publicador

PERGAMON-ELSEVIER SCIENCE LTD

Relação

Tetrahedron Letters

Direitos

closedAccess

Copyright PERGAMON-ELSEVIER SCIENCE LTD

Palavras-Chave #synthesis #natural products #furanoheliangolides #eremantholides #Stryker`s reagent #OCCURRING TERPENE DERIVATIVES #SCHULTZ-BIP COMPOSITAE #SESQUITERPENE LACTONES #VANILLOSMOPSIS-ERYTHROPAPPA #(+)-EREMANTHOLIDE-A #15-DEOXYGOYAZENSOLIDE #CONSTITUENTS #INHIBITION #Chemistry, Organic
Tipo

article

original article

publishedVersion